2050-07-9
- Product Name：4-methyl-1-phenylpentan-1-one
- Molecular Formula：C12H16 O
- Purity：99%
- Molecular Weight：176.258
Product Details;
CasNo： 2050-07-9
Molecular Formula： C12H16 O
Quality Factory Customized Supply Wholesale 4-methyl-1-phenylpentan-1-one 2050-07-9
- Molecular Formula:C12H16 O
- Molecular Weight:176.258
- Vapor Pressure:0.0185mmHg at 25°C
- Melting Point:-1°C
- Refractive Index:1.5330 (estimate)
- Boiling Point:253.2°Cat760mmHg
- Flash Point:99.4°C
- PSA：17.07000
- Density:0.94g/cm3
- LogP:3.30550
4-methyl-1-phenylpentan-1-one(Cas 2050-07-9) Usage
|
Uses |
4-Methyl-valerophenone is an intermediate used in the synthesis of a-Pyrrolidinoisohexanophenone (Hydrochloride) (P841230), which is a phenone derivative used for research purposes. |
InChI:InChI=1/C12H16O/c1-10(2)8-9-12(13)11-6-4-3-5-7-11/h3-7,10H,8-9H2,1-2H3
2050-07-9 Relevant articles
KOtBu/DMSO Catalytic System for Isomerization of Allylic Alcohols to Ketones
Sai, Masahiro
, (2022/04/03)
The isomerization of allylic alcohols is...
Iron-Catalyzed, Iminyl Radical-Triggered Cascade 1,5-Hydrogen Atom Transfer/(5+2) or (5+1) Annulation: Oxime as a Five-Atom Assembling Unit
Chen, Ying-Chun,Du, Fei,Jiang, Kun,Liang, Wu,Ouyang, Qin,Shuai, Li,Wei, Ye,Yang, Jie
supporting information, p. 19222 - 19228 (2020/08/25)
By integration of iminyl radical-trigger...
Copper-Catalyzed Oxidative Fragmentation of Alkynes with NFSI Provides Aryl Ketones
Chen, Hanfei,Cheng, Hao,Huang, Yifan,Jin, Chaochao,Song, Weihan,Tan, Chen,Tan, Jiajing,Tang, Lin,Yang, Fang,Zhang, Shuaifei
supporting information, (2020/11/03)
A copper-catalyzed oxidative cleavage re...
Ni-Catalyzed β-Alkylation of Cyclopropanol-Derived Homoenolates
Mills, L. Reginald,Zhou, Cuihan,Fung, Emily,Rousseaux, Sophie A. L.
supporting information, p. 8805 - 8809 (2019/11/03)
Metal homoenolates are valuable syntheti...
2050-07-9 Process route
-
-
78-83-1
2-methyl-propan-1-ol
-
-
98-86-2
acetophenone
-
-
2050-07-9
4-methyl-1-phenylpentan-1-one
| Conditions | Yield |
|---|---|
|
With
potassium phosphate tribasic trihydrate; 5%-palladium/activated carbon;
In
water;
at 180 ℃;
for 1.5h;
Microwave irradiation;
|
85% |
|
With
(S)-methyl 2-(2-(1H-benzo[d][1,2,3]triazol-1-yl)acetamido)propanoate; sodium t-butanolate;
In
toluene;
at 110 ℃;
for 48h;
Schlenk technique;
Inert atmosphere;
|
81% |
|
With
potassium phosphate tribasic trihydrate; C39H32Cl2N5PRu;
In
tert-Amyl alcohol;
at 120 ℃;
for 4h;
Inert atmosphere;
Schlenk technique;
|
80% |
|
With
bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; potassium hydroxide;
at 110 ℃;
for 0.166667h;
Inert atmosphere;
|
76% |
|
With
C38H43ClIrN2O2P; caesium carbonate; silver(I) triflimide;
for 24h;
Time;
Schlenk technique;
Inert atmosphere;
Reflux;
|
67% |
|
With
lithium tert-butoxide;
In
toluene;
at 110 ℃;
for 12h;
Inert atmosphere;
|
63% |
|
With
C38H43IrN2PS2(1+)*CF3O3S(1-); caesium carbonate;
In
tert-Amyl alcohol;
at 120 ℃;
for 24h;
Schlenk technique;
Inert atmosphere;
|
49% |
|
With
potassium hydroxide;
dichlorotetrakis(dimethyl sulfoxide)ruthenium(II);
In
1,4-dioxane;
at 80 ℃;
for 24h;
|
5% |
|
With
potassium hydroxide;
bis(1,5-cyclooctadiene)diiridium(I) dichloride; triphenylphosphine;
at 100 ℃;
for 4h;
|
|
|
With
bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; potassium hydroxide;
at 110 ℃;
for 1h;
Inert atmosphere;
|
-
-
1116-40-1
triisobutylamine
-
-
98-86-2
acetophenone
-
-
2050-07-9
4-methyl-1-phenylpentan-1-one
| Conditions | Yield |
|---|---|
|
With
ruthenium trichloride; triphenylphosphine;
In
1,4-dioxane;
at 180 ℃;
for 40h;
|
77% |
|
With
5%-palladium/activated carbon;
In
toluene;
at 120 ℃;
for 40h;
regioselective reaction;
Inert atmosphere;
|
32% |
2050-07-9 Upstream products
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-
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2050-07-9 Downstream products
-
30299-39-9
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-
19988-49-9
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-
17314-92-0
(3,3-dimethylbutyl)benzene
-
4215-86-5
isohexylbenzene
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